학술논문
Prediction of the thermodynamic data of the pseudobinary alkali halide-lanthanide halide condensed systems
Document Type
Academic Journal
Source
Journal of Alloys and Compounds. Feb 28, 2008, Vol. 451 Issue 1-2, p679, 3 p.
Subject
Language
English
ISSN
0925-8388
Abstract
To link to full-text access for this article, visit this link: http://dx.doi.org/10.1016/j.jallcom.2007.04.085 Byline: Jan KapaAa, Marta BochyAska, Katarzyna Broczkowska, Iwona Rutkowska Keywords: Rare earth alloys and compounds; Phase diagrams; Thermodynamic modeling Abstract: The database of the thermodynamic properties of the alkali halide-lanthanide halide systems was built and completed. The procedures of interpolation and extrapolation of the unavailable data were considered. The accuracy of the predicted thermodynamic properties was estimated. The correlations between the selected thermodynamic properties were studied. For the CsCl-PmCl.sub.3 system the unknown thermodynamic data were predicted. The internal compatibility of the obtained data was checked and the phase diagram was calculated using the CALPHAD method. Author Affiliation: WrocAaw University of Technology, WybrzeA1/4e WyspiaAskiego 27, 50-370 WrocAaw, Poland