부산대학교 도서관

The one-pot synthesis of N-doped graphene quantum dots (GQDs), capped with a positively charged polyamine (trien), has been realized through a microwave-assisted pyrolysis on solid L-glutamic acid and trien in equimolar amounts. The resulting positively charged nanoparticles are strongly emissive in aqueous solutions and are stable for months. The interaction with the anionic tetrakis(4-sulphonatophenyl)porphyrin (TPPS[sub.4]) has been investigated at neutral and mild acidic pH using a combination of UV/vis absorption spectroscopy together with static and time-resolved fluorescence emission. At pH = 7, the experimental evidence points to the formation of a supramolecular adduct mainly stabilized by electrostatic interactions. The fluorescence emission of the porphyrin is substantially quenched while GQDs remain still emissive. On decreasing the pH, protonation of TPPS[sub.4] leads to formation of porphyrin J-aggregates through the intermediacy of the charged quantum dots.
Author(s): Mariachiara Sarà [1]; Salvatore Vincenzo Giofrè [1]; Salvatore Abate [1]; Mariachiara Trapani [2]; Rosaria Verduci [3]; Giovanna D’Angelo [3]; Maria Angela Castriciano [1]; Andrea Romeo [1,2]; Giovanni Neri [4]; [...]