학술논문

Ru-functionalized Ni-doped dual phases of [alpha]/[gamma]-Fe.sub.2O.sub.3 nanosheets for an optimized acetone detection
Document Type
Report
Source
Journal of Nanostructure in Chemistry. December, 2023, Vol. 13 Issue 6, p577, 13 p.
Subject
Acetone
Glycerin
Glycerol
Sensors
Ferric oxide
Language
English
Abstract
Lately novel strategies to enhance the sensing properties on iron oxide have been proposed to achieve high performance gas sensors for acetone detection. In this working report, the synthesis of iron-glycerate (Fe-Gly) using glycerol to combine with Fe.sup.3+ is first presented. Depending on the thermal treatment, this compound can evolve into [gamma]-Fe.sub.2O.sub.3, [alpha]/[gamma]-Fe.sub.2O.sub.3 and [alpha]-Fe.sub.2O.sub.3. [alpha]/[gamma]-Fe.sub.2O.sub.3 shows better sensing performance as far as acetone detection is concerned. Using the dual phases of [alpha]/[gamma]-Fe.sub.2O.sub.3 as a fundamental building block, their sensing properties were further improved using Ni doping and Ru nanoparticles functionalization. The high response and selectivity to acetone detection was ascribed to the synergistic effects of unique nanosheets, mixed phases, rich oxygen vacancies and excellent catalytic activity of Ru nanoparticles. Graphical abstract
Author(s): Ruonan Tian [sup.1], Zeyuan Gao [sup.1], Ruifeng Lang [sup.1], Na Li [sup.1], Huilin Gu [sup.1], Gang Chen [sup.1], Hongtao Guan [sup.1], Elisabetta Comini [sup.2], Chengjun Dong [sup.1] Author Affiliations: [...]