학술논문
Formation, spectral, electrochemical, and photochemical behavior of zinc N-confused porphyrin coordinated to imidazole functionalized fullerene dyads
Document Type
Academic Journal
Author
Source
Inorganic Chemistry. June 26, 2006, Vol. 45 Issue 13, p5057, 9 p.
Subject
Language
English
ISSN
0020-1669
Abstract
Zinc N-confused porphyrin (ZnNCP), a structural isomer of zinc tetraphenylporphyrin, were used to construct donor-acceptor dyads, as a donor and fullerene as an electron acceptor, with imidazole-appended fulleropyrrolidine and are characterized by optical absorption and emission, ESI-mass, NMR and electrochemical methods. Evidence of photoinduced charge separation from the singlet excited ZnNCP to the appended fullerene is established from time-resolved emission and nanosecond transient absorption studies.