학술논문
Synthesis and characterization of Co(II), Cu(II) and Zn(II) complexes with 1,1-cyclobutanedicarboxylic acid
Document Type
Report
Source
Polyhedron. Feb 13, 2006, Vol. 25 Issue 3, p687, 8 p.
Subject
Language
English
ISSN
0277-5387
Abstract
To link to full-text access for this article, visit this link: http://dx.doi.org/10.1016/j.poly.2005.07.044 Byline: Zofia RzAczyAska (a), Agata Bartyzel (a), ElA1/4bieta Olszewska (a), Wanda Sawka-Dobrowolska (b) Keywords: Cobalt 1,1-cyclobutanedicarboxylate; Copper 1,1-cyclobutanedicarboxylate; Zinc 1,1-cyclobutanedicarboxylate; X-ray analysis; Crystal structure; IR spectra; Thermal analysis; TG-FTIR analysis Abstract: Polycrystalline complexes of Co(C.sub.6H.sub.6O.sub.4)*2H.sub.2O, Cu(C.sub.6H.sub.6O.sub.4), and Zn.sub.2(C.sub.6H.sub.6O.sub.4).sub.2 *3H.sub.2O were synthesized. The complexes were characterized by elemental analysis, IR spectroscopy, thermal analysis (TG, DSC/DTA, and TG-FTIR) and X-ray analysis. During recrystallization, single crystals of [Co.sub.2(C.sub.6H.sub.6O.sub.4).sub.2(H.sub.2O).sub.3] and [Cu(C.sub.6H.sub.6O.sub.4)H.sub.2O] were obtained. Author Affiliation: (a) Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-SkAodowska University, 20-031 Lublin, Poland (b) Faculty of Chemistry, University of WrocAaw, 50-383 WrocAaw, Poland Article History: Received 4 April 2005; Accepted 14 July 2005