학술논문

An efficient catalyst system for Pd-catalyzed amination of [2.2] paracyclophanyl bromides
Document Type
Report
Source
Journal of Organic Chemistry. Sept 4, 2009, Vol. 74 Issue 17, p6867
Subject
Amines -- Chemical properties
Bromides -- Chemical properties
Cyclophanes -- Chemical properties
Cyclophanes -- Structure
Palladium catalysts -- Chemical properties
Language
English
ISSN
0022-3263
Abstract
The development of a practical Buchwald-Hartwig amination of [2.2]paracyclophanyl bromides with benzhydrylideneamine is described. The method has provided a facile route to a variety of imino and amino [2.2]paracyclophanes that are otherwise not readily synthesized.