학술논문
A series of the twelve-vertex ferratricarbollides (2-(eta(super 5)-C5H5)-9-X-closo-2,1,7,9-FEC3B8H10) (where X = H2N, MeHN, Me2N, Bu(super t)HN, Bu(super t)(Me)N). A highly stable metallatricarbaborane system with amine functions in the para position to the metal center
Document Type
Academic Journal
Author
Source
Inorganic Chemistry. June 14, 1999, Vol. 38 Issue 12, p2775, 6 p.
Subject
Language
ISSN
0020-1669
Abstract
Research was conducted to examine two procedures leading to smooth rearrangement complexation of compounds of type 7-XH-nido-7,8,9-C3B8H10. A series of new metallatricarbollide isomers having chemically flexible amine functionalities in p-positions with respect to the metal center and are isomeric with the unsubstituted complex (2-(eta(super 5)-C5H5)-closo-2,1,7,10-FeC3B8H11). High-field NMR spectroscopy and mass spectrometry were used to establish the structures of all compounds.