학술논문
The derivatives of the 7, 8, 9 -series of tricarbollides. Preparation and structural characterization of the 11-vertex tricarboranes 7-L-nido-7, 8, 9-C3B8H10 (L = amines)
Document Type
Academic Journal
Author
Source
Inorganic Chemistry. June 5, 1996, Vol. 35 Issue 12, p3635, 8 p.
Subject
Language
ISSN
0020-1669
Abstract
Monocarbon cage-insertions for polyhedral borons substrates and isonitriles are characterized by endo-substitution through derivatives of ligand substitutions. Cluster borane anions react with cyanide anions and isonitriles by monocarbon insertion. Tricarbaboranes are formed by the reaction of 10-vertex nido dicarborane compounds. The unsubstituted tricarbaboranes are formed by the reactions of cyanide and isonitrile. The cluster insertion processes are initiated by endo-attack by the negative insertion carbon at the positively charged C(6) anion site.