학술논문
Recent XAS studies into Homogeneous metal catalyst in fine chemical and pharmaceutical syntheses
Document Type
Report
Author
Source
Chemistry Central Journal. June 18, 2015, Vol. 9
Subject
Language
English
Abstract
A brief review of studies using X-ray Absorption Spectroscopy (XAS) to investigate homogeneous catalytic reactions in fine chemical and pharmaceutical context since 2010 is presented. The advantages of the techniques over traditional lab-based analytical tools, particularly when NMR spectroscopy fails to deliver mechanistic insights, are summarised using these examples. A discussion on the current limitations of the techniques and challenges in the near future is also included. Graphical abstract: A minireview of recent developments in application of X-ray Absorption Spectroscopy as an effective mechanistic tool to synthetic catalytic reactions relevant to fine chemical and pharmaceutical syntheses. [end caption] Keywords: X-ray absorption spectroscopy, Homogeneous catalysis, Mechanism
Author(s): Grant J Sherborne[sup.1] and Bao N Nguyen[sup.1] XAS has been very successfully applied as a technique to study heterogeneous catalysts [1, 2]. Electronic and structural information can be extracted […]
Author(s): Grant J Sherborne[sup.1] and Bao N Nguyen[sup.1] XAS has been very successfully applied as a technique to study heterogeneous catalysts [1, 2]. Electronic and structural information can be extracted […]