학술논문
Copper chloride-catalyzed and hydrochloric acid-mediated chemoselective protiodestannylations of alkyl (Z)- or (E)-2,3-bis(trimethylstannyl)-2-alkenoates. Stereoselective preparation of alkyl (E)- and (Z)-3-trimethylstannyl-2-alkenoates
Document Type
Academic Journal
Source
Journal of Organic Chemistry. August 22, 1997, Vol. 62 Issue 17, p6034, 8 p. table
Subject
Language
ISSN
0022-3263
Abstract
A novel method of synthesizing alkyl (E)- and (Z)-3-trimethylstannyl-2-alkenoates was developed through the use of trimethylstannylcopper(I) reagents. The design featured removal of 2-trimethylstannyl function following reaction of copper(I) chloride with N,N-dimethylformamide. The reaction resulted in high yield alkyl (E)-3-trimethylstannyl-2-alkenoates.