학술논문
Characterization of species present in aqueous solutions of (hydroxy(mesyloxy)iodo)benzene and (hydroxy(tosyloxy)iodo)benzene
Document Type
Academic Journal
Source
Journal of the American Chemical Society. Oct 15, 1997, Vol. 119 Issue 41, p9614, 10 p.
Subject
Language
ISSN
0002-7863
Abstract
(Hydroxy(mesyloxy)iodo)benzene (HMIB) and its tosyloxy analog (HTIB) are stable, crystalline organoiodine complexes which are soluble in water at natural pH. UV-vis and NMR spectroscopy was used, together with potentiometric titration data, to show the presence of dimeric mu-oxodiiodine species in aqueous solution. The data shows that HMIB and HTIB occur in aqueous solution as fully solvated ions, a free hydroxy(phenyl)iodonium ion and an organosulfonate ion.