학술논문
Reactivity of nitric oxide with simple short-lived radicals in aqueous solutions
Document Type
Academic Journal
Source
Journal of the American Chemical Society. Dec 14, 1994, Vol. 116 Issue 25, p11465, 5 p. table
Subject
Language
ISSN
0002-7863
Abstract
A study using pulse radiolysis technique of the reactivity of nitric oxide (NO) with SCN(sub 2)(super -), Br(sub 2)(super -), Co(sub 2)(super -), CO(sub 3)(super -) and ethyl alcohol radicals reveals that NO reacts with oxidizing free radicals SCN(sub 2)(super -) and Br(sub 2)(super -) to form NOX(sub 2)(super -) adducts which hydrolyze to NO(sub 2)(super -), while reactions with ethanol radicals yields adducts that rearrange to stable oximes and hydroxamic acids. NO reacts with CO(sub 3)(super -) via O-transfer to yield NO(sub 2)(super -) while excess NO reacts with Co(sub 2)(super -) to form (N2O2)-, NO reacts with Br(sub 2)(super -) to form (NOBR2)- at rates similar to that of (NO(SCN)2)-.