학술논문
O-H stretch excitation in methyl and ethyl hydroperoxides
Document Type
Academic Journal
Source
Journal of Physical Chemistry A. Nov 4, 2004, Vol. 108 Issue 44, p9492, 8 p.
Subject
Language
English
ISSN
1089-5639
Abstract
Laser photoacoustic spectroscopy is used to obtain vibrational overtone spectra in the regions of four and five quanta of O-H stretch for gas-phase methyl, ethyl and tert-butyl hydroperoxide. Interpretation of spectral features using a vibration-torsion model for ROOH molecules, where excitation of torsional motion about the vibration-torsion accompanies vibrational excitation, yields plausible fits to the spectra.