학술논문
At point of use sono-electrochemical generation of hydrogen peroxide for chemical synthesis: The green oxidation of benzonitrile to benzamide
Document Type
Report
Author
Source
Ultrasonics - Sonochemistry. Feb, 2007, Vol. 14 Issue 2, p113, 4 p.
Subject
Language
English
ISSN
1350-4177
Abstract
To link to full-text access for this article, visit this link: http://dx.doi.org/10.1016/j.ultsonch.2006.05.007 Byline: Jose Gonzalez-Garcia (a), Ludovic Drouin (b), Craig E. Banks (a), Biljana A ljukiA (a), Richard G. Compton (a) Keywords: Sono-electrochemistry; Hydrogen peroxide; Green chemistry Abstract: At point of use generation of synthetically useful quantities of hydrogen peroxide in a non-optimized sono-electrochemical cell is reported. Proof-of-concept of the use of this procedure for green synthesis is given through the oxidation of benzonitrile to benzamide with yields similar to those obtained via bulk chemical synthesis. Author Affiliation: (a) Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, United Kingdom (b) Chemistry Research Laboratory, Oxford University, 12 Mansfield Road, Oxford OX1 3TA, United Kingdom Article History: Received 22 April 2006; Revised 31 May 2006; Accepted 31 May 2006