학술논문
Voltammetric and electrochemical ESR studies of oxidation reactions mediated by tris(4-bromophenyl)amine in acetonitrile
Document Type
Academic Journal
Author
Source
Journal of Physical Chemistry B. Feb 16, 2006, Vol. 110 Issue 6, p2681, 11 p.
Subject
Language
English
ISSN
1520-6106
Abstract
The electrochemical oxidation of tris(4-bromophenyl)amine (TBPA) in the presence of 2,6-lutidine is examined in acetonitrile. Voltammetric and spectroscopic studies show that the electrogenerated triaryl aminium radical cation oxidizes 2,6-lutidine in an electrochemical mechanism and a homogeneous electron transfer equilibrium exists between electrogenerated species TBPA and 2,6-lutidine.