학술논문
chelate complexes (eta(super 5)-C(sub 5)Me(sub 5))IrL(sub 2)(L(sub 2) = TsNCH(sub 2)CH(sub 2)NTS, TsNCH(sub 2)CO)sub 2), CO(sub 2)CO(sub 2)
Document Type
Academic Journal
Author
Source
Inorganic Chemistry. June 12, 2000, Vol. 39 Issue 12, p2493, 7 p.
Subject
Language
English
ISSN
0020-1669
Abstract
The roles of carboxylato and sulfonamido ligands is made clear by a comparative synthetic, structural and thermodynamic study of coordinatively unsaturated chelate complexes, which are monomeric in solution and in the solid states. However, the oxalato complex exists as a 'n' oligomer or polymer that serves as a versatile precursor to monomeric adducts 6-L.