학술논문

An efficient process for Pd-catalyzed C-N-coupling reactions of aryl iodides: insight into controlling factors
Document Type
Academic Journal
Source
Journal of the American Chemical Society. April 29, 2009, Vol. 131 Issue 16, 5766-5768
Subject
Palladium catalysts -- Chemical properties
Palladium catalysts -- Research
Arylation -- Research
Chemistry
Language
English
ISSN
0002-7863
Abstract
The Pd-catalyzed C-N cross-coupling reactions of aryl iodides are examined and NaI is shown to have inhibitory effect on these processes. Catalyst systems based on biarylphosphine ligands are used for reacting aryl iodides with an array of primary and secondary amines in high yields.