학술논문
Evidence of a surprising channeling of ring-opening energy to the H2 product in the H + c-C3H6 [right arrow] H2 + C3H5 abstraction reaction
Document Type
Academic Journal
Author
Source
Journal of Physical Chemistry A. Oct 16, 2003, Vol. 107 Issue 41, p8380
Subject
Language
English
ISSN
1089-5639
Abstract
The product energy disposal in the abstraction reaction H + c-C3H6 [right arrow] H2(v', j') + C3H5 at 1.6 eV collision energy is characterized by quantum-state-selective, doppler-resolved REMPI detection of the H2(v', j') product. The H2(v', j') product is observed with total energy, translational plus rotational plus vibrational, in excess of the total energy available if the C3H5 product is a cyclopropyl radical.