학술논문
Synthesis and single crystal investigation of two-dimensional rectangular network [M-(4,4'-bpy)(Phth)(H2o)](sub n).2H2O with small neutral cavities
Document Type
Academic Journal
Source
Inorganic Chemistry. July 30, 2001, Vol. 40 Issue 16, 4078-4080
Subject
Language
English
ISSN
0020-1669
Abstract
Two isostructural neutral coordination polymers [M(4,4'-bpy)(phth)(H2O)](sub n).2H2O, where M = Co(super 2+), Cd (super 2+), comprising rectangular grids with each cavity enclosed by two 4,4'-bipyridine (4,4'-bpy) and two phthalate (phth) ligands, which superpose in an offset fashion reducing the channel size to include two water molecules, are synthesized and structurally characterized by single crystal X-ray diffraction.