학술논문

Spectroscopic, structural, and mass spectrometric studies on two systematic series of dithiabismuth(II) heterocycles: identification of bismuthenium cations and their solvent complexes
Document Type
Academic Journal
Source
Journal of the American Chemical Society. April 3, 1996, Vol. 118 Issue 13, p3225, 8 p. table
Subject
Heterocyclic compounds -- Research
Bismuth -- Research
Language
ISSN
0002-7863
Abstract
Vibrational spectroscopic and x-ray crystallographic observations of two classes dithiabismuth heterocycles synthesized via quantitative metathesis were carried out. The heterocycles were chloro-substituted monocycles and tethered bicyclic derivatives. The observations revealed the occurence of monocyclic bismuthenium cations as the dominant dissociation product in their synthesis.