학술논문

BACKFLIP: Identification of Materials and Changes Upon Aging of Emerging Fluoropolymer-Free and Industry-Benchmark PV Backsheets
Document Type
Conference
Source
2021 IEEE 48th Photovoltaic Specialists Conference (PVSC) Photovoltaic Specialists Conference (PVSC), 2021 IEEE 48th. :1842-1847 Jun, 2021
Subject
Components, Circuits, Devices and Systems
Power, Energy and Industry Applications
Photovoltaic systems
Degradation
Temperature
Polyethylene
Glass
Mechanical factors
Safety
backsheet
DSC
WAXS
FTIR
DuraMAT
polyolefin
weathering
Language
Abstract
Extending lifetimes of photovoltaic (PV) modules and decreasing manufacturing and decommissioning costs are motivating research of novel PV module backsheet materials. Backsheet integrity is critical to the safety and performance of a PV module, however, the polymeric materials are often vulnerable to environmental degradation. The long-term durability of emerging polyolefin (PO) materials is being examined to inform regarding the possible replacement of laminated backsheets containing polyethylene terephthalate (PET) cores and fluoropolymer protective inner/outer layers. This study compares traditional PET-based backsheets with novel, co-extruded, and recyclable PO-based backsheets after being subjected to hygrometric and UV photolytic accelerated weathering. A large set of characterization methods will compare physical, chemical, structural, mechanical, and insulating properties of these backsheets and the resulting mini-module (MiMo) PV performances. The study of chemical composition, glass- and phase-transition temperatures, degree of crystallinity, and crystalline structure are described here.