학술논문

Characterization of Arsenic Doped CdTe Layers and Solar Cells
Document Type
Conference
Source
2017 IEEE 44th Photovoltaic Specialist Conference (PVSC) Photovoltaic Specialist Conference (PVSC), 2017 IEEE 44th. :1193-1195 Jun, 2017
Subject
Aerospace
Components, Circuits, Devices and Systems
Engineered Materials, Dielectrics and Plasmas
Engineering Profession
Fields, Waves and Electromagnetics
Photonics and Electrooptics
Power, Energy and Industry Applications
II-VI semiconductor materials
Cadmium compounds
Doping
Arsenic
Temperature measurement
Photovoltaic cells
Photovoltaic systems
electroluminescence
imaging
photovoltaic cells
photovoltaic systems
reliability
silicon
solar energy
solar power generation
Language
Abstract
Polycrystalline CdTe solar cells with hole carrier-density greater than 10 16 cm −3 have been realized by doping the absorber with Arsenic. The high carrier concentration requires a large excess of Arsenic in the film implying only percent level doping activation. Appearance of a sub-bandgap peak in the photoluminescence (PL) spectrum is linked with the activation of the Arsenic dopant. Low temperature PL measurements confirm an acceptor level at 90 meV from the valence band, which is consistent with reported literature values. Additional features in the PL spectra suggests the presence of sub-band defects. Understanding the origin for these features may enable the high efficiency potential of group-V doping.