학술논문

Analysis of Interfacial Water in Clay by High Frequency Dielectric Relaxation Spectroscopy
Document Type
Conference
Source
2021 13th International Conference on Electromagnetic Wave Interaction with Water and Moist Substances (ISEMA) Electromagnetic Wave Interaction with Water and Moist Substances (ISEMA), 2021 13th International Conference on. :1-5 Jul, 2021
Subject
Engineered Materials, Dielectrics and Plasmas
Fields, Waves and Electromagnetics
Signal Processing and Analysis
Temperature measurement
Water
Temperature dependence
Soil
Dielectric measurement
Dielectrics
Minerals
Relaxation behavior
bound water
electrical modulus
clays
open ended probe
Language
Abstract
Geotechnical application of high frequency (radio to microwave) electromagnetic (HF-EM) techniques is based on the relationship between constitutive HF-EM material properties and soil structural or state parameters such as water content, density, temperature and stress strain state. An unresolved problem in the theoretical modeling of HF-EM properties is the interaction of the aqueous pore solution and mineral phases, especially in fine grained soils containing clay minerals. Against this background temperature (-2 to 25 °C) and frequency (50 MHz to 5 GHz) dependent dielectric material properties of two water saturated clays (illite-chlorite, montmorillonite) were measured with open ended coaxial line technique. The impact of dielectric relaxation processes below 1 GHz were analysed based on a master plot for the electrical modulus representation. In case of illite-chlorite the deviation from a Debye-type characteristic is small indicating that a Maxwell-Wagner effect dominates the interaction of the aqueous pore solution and soil particles. In contrast montmorillonite shows a significant deviation from Debye-type characteristics with asymmetrical relaxation time distribution. Hence, an additional HF relaxation processes are hidden behind the dominated Maxwell-Wagner process.