학술논문

Development of a Sub-10-ppm Limit of Detection Lateral Nanogap Gas Sensor
Document Type
Periodical
Source
IEEE Sensors Letters IEEE Sens. Lett. Sensors Letters, IEEE. 7(9):1-4 Sep, 2023
Subject
Components, Circuits, Devices and Systems
Robotics and Control Systems
Communication, Networking and Broadcast Technologies
Signal Processing and Analysis
Gas detectors
Sensors
Electrodes
Testing
Nanoscale devices
Nanostructures
Nitrogen
Chemical and biological sensors
electrochemical and gas sensors
atomic layer deposition (ALD) exposure mode
biomarker
conformality
hexanal
lateral nano-gap
limit of detection (LOD)
on%2Foff<%2Fsc>+ratio%22">on/off ratio
sub-10-nm
sub-10-parts per million (ppm)
volatile organic compounds (VOCs)
wake-up gas sensor
Language
ISSN
2475-1472
Abstract
This letter reports a wake-up gas sensor based on a lateral nanogap structure that is capable of increasing nanogap surface area by 11.2 times and thus improving the limit-of-detection (LOD) by 10 times down to 5 parts per million (ppm) in comparison with the previous vertical nanogap structure. Unlike the vertical nanogap structure with a suspended membrane, this lateral nanogap structure avoided fragile components and thus was able to reliably release a relatively large surface area of a 5-nm gap structure. The microfabricated lateral nanogap structure spanned over an enlarged area of 700 µm 2 , in comparison with the maximum area of 62.5 µ m 2 in the previous vertical gap structure, with the highest surface-area-to-nanogap-size aspect ratio of 130 µm 2 /nm. When coated with a customized linker, it demonstrated (1) a gas sensing capability down to 5 ppm under the exposure of hexanal at a flow rate of 50 sccm, (2) a high wake-up on current of 460 nA, and (3) an on/off ratio of 1.51, which are sufficient for detection.