학술논문

Properties of calcium-barium titanate dielectrics
Document Type
Conference
Source
1948 Conference on Electrical Insulation Electrical Insulation, 1948 Conference on. :79-83 Oct, 1948
Subject
Engineered Materials, Dielectrics and Plasmas
Fields, Waves and Electromagnetics
Power, Energy and Industry Applications
Absorption
Ceramics
Firing
Heat treatment
Temperature
Dielectric constant
Raw materials
Language
Abstract
Dielectrics having compositions in the system 3CaO:TiO 2 -BaTiO 3 -TiO 2 were matured (less than 0.1 percent absorption) at 1260° to 1500°C. Data are given for the compositions, heat treatments, absorption, shrinkage, and for K, the dielectric constant, and Q, the reciprocal of the power factor at 25°C and frequencies of 50, 1000, and 20,000 kc/s, and at 3,000 mc/s when K is not greater than 50. Values of K were also determined at 1 mc/s and various temperatures from −60° to +85°C. At 25°C and 1 mc/s, K ranged from 34 to 2670 and Q from 27 to 10,000. Lowest values of Q were associated with specimens of high baria content. The values of K decreased and those of Q increased for several weeks after the dielectrics. Were matured when the percentage of titania was less than 50 and that of baria greater than about 30. Linear thermal expansion (25° to 700°C) ranged from 0.65 to 0.87 percent. The specimens of composition 3CaO:TiO 2 disintegrated after a few weeks when exposed to room conditions, and all the dielectrics containing less than 50 percent of titania and greater than about 30 percent of calcia deteriorated greatly in Q value after storage for a year.