학술논문

Amine-Functionalized Capacitive Carbon Dioxide Sensor Performance as a Function of Temperature and Sensing Film Thickness
Document Type
Periodical
Source
IEEE Sensors Journal IEEE Sensors J. Sensors Journal, IEEE. 21(13):14645-14654 Jul, 2021
Subject
Signal Processing and Analysis
Communication, Networking and Broadcast Technologies
Components, Circuits, Devices and Systems
Robotics and Control Systems
Sensors
Temperature sensors
Capacitive sensors
Heating systems
Temperature measurement
Chemical sensors
Electrodes
Carbon dioxide sensor
interdigitated capacitor
amine-functionalized chemical sensor
Language
ISSN
1530-437X
1558-1748
2379-9153
Abstract
This paper systematically investigates sensor performance of amine-functionalized, microfabricated capacitive carbon dioxide (CO 2 ) sensors as a function of sensor temperature and sensing film thickness. The sensor comprises a 1 mm by 1 mm interdigitated electrode structure with $2~\mu \text{m}$ line width and $2~\mu \text{m}$ line spacing, surrounded by a resistive temperature sensor and a resistive heater. A mixture of 3-aminopropyltrimethoxysilane and propyltrimethoxysilane was spray-coated onto the sensors and the CO 2 response was measured in a gas mixing system. Using a 100 nm thick sensing film, a maximum sensor sensitivity of −1.2%/1,000ppm CO 2 concentration was obtained with response times of 5-10 minutes at a sensor temperature of 85°C. The sensor sensitivity decreases for higher and lower temperatures while the sensor response time monotonically decreases with increasing sensor temperature. Thicker sensing films improve sensor sensitivity at the expense of a longer response time.