학술논문

Single molecular vibrational relaxation dynamics and adsorbate fluctionality
Document Type
Conference
Source
2015 Conference on Lasers and Electro-Optics (CLEO) Lasers and Electro-Optics (CLEO), 2015 Conference on. :1-2 May, 2015
Subject
General Topics for Engineers
Photonics and Electrooptics
Raman scattering
Fluctuations
Temperature dependence
Cryogenics
Real-time systems
Vibration measurement
Language
ISSN
2160-8989
Abstract
Tip-enhanced Raman spectroscopy at cryogenic temperatures probes the intrinsic linewidths of vibrational modes. Temperature dependent investigation of small ensembles reveals ultrafast vibrational relaxation dynamics, conformational heterogeneity, and single molecule fluctionality on the time scale of seconds.