학술논문

18.2% (AM1.5) efficient GaAs solar cell on optical-grade polycrystalline Ge substrate
Document Type
Conference
Source
Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996 Photovoltaic Specialists Conference, 1996., Conference Record of the Twenty Fifth IEEE. :31-36 1996
Subject
Photonics and Electrooptics
Components, Circuits, Devices and Systems
Engineered Materials, Dielectrics and Plasmas
Power, Energy and Industry Applications
Gallium arsenide
Photovoltaic cells
Dark current
Optical materials
Voltage
Lighting
Optical devices
Crystallization
Doping
Temperature
Language
ISSN
0160-8371
Abstract
In this work, the authors present GaAs material and device-structure optimization studies that have led to achieve a open-circuit voltage of /spl sim/1 volt and a best solar cell efficiency of 18.2% under AM1.5G illumination, for a 4 cm/sup 2/ area GaAs cell on commercially-available, cast, optical-grade polycrystalline Ge substrate. This V/sub /spl infin// is almost 70 mV higher than on their previously-reported best GaAs cell on similar substrates. They discuss the growth of high-quality GaAs-AlGaAs layers, across the various crystalline orientations of a polycrystalline Ge substrate, important for obtaining good device performance. Optimization studies of the minority-carrier properties of GaAs layers on poly-Ge substrates have revealed that lifetime-spread across various grains can be reduced through the use of lower doping for the Al/sub 0.8/Ga/sub 0.2/As confinement layers. The cell-structure optimization procedures for improved V/sub /spl infin// and cell efficiency, include the use of thinner emitters, a spacer layer near the p/sup +/-n junction and an improved window layer. An experimental study of dark currents in these junctions, with and without the spacer, as a function of temperature (77 K to 288 K) is presented indicating that the spacer reduces the tunneling contribution to dark current.