학술논문

Comparison of gettering effects during phosphorus diffusion for one- and double-sided emitters
Document Type
Conference
Source
Conference Record of the Thirty-first IEEE Photovoltaic Specialists Conference, 2005. Photovoltaic Specialists Conference Photovoltaic Specialists Conference, 2005. Conference Record of the Thirty-first IEEE. :1051-1054 2005
Subject
Photonics and Electrooptics
Components, Circuits, Devices and Systems
Engineered Materials, Dielectrics and Plasmas
Power, Energy and Industry Applications
Gettering
Photovoltaic cells
Throughput
Production
Spraying
Diffusion processes
Doping
Fluorescence
Performance evaluation
Aluminum
Language
ISSN
0160-8371
Abstract
A key issue for future solar cell processes is a diffusion sequence which enables fast and clean production, for example by spin-on and spray-on dopants. These diffusion processes have in common that the emitter diffusion is applied on one wafer side, whereas the POCl/sub 3/ emitter process leads to double-sided doping. For higher throughput the POCl/sub 3/ process could be adapted by using one slot for two wafers. This so called back-to-back process leads to one-sided emitters and increases industrial throughput but could result in lower cell efficiency due to reduced gettering during phosphorus diffusion. In this study we investigate the difference in solar cell performance for cells processed in a back-to-back and standard POCl/sub 3/ process. Furthermore, X-ray fluorescence and SIMS measurements were performed on Cz material to study the effect of emitter over-compensation by aluminium. These experiments should clarify if the phosphorus of double-sided emitter cells is partly overcompensated or diffuses into the Al layer of the rear contact.