학술논문

Long-term data reflect nitrogen pollution in Estonian rivers
Document Type
article
Source
Hydrology Research, Vol 53, Iss 12, Pp 1468-1479 (2022)
Subject
manure
mineral fertilisers
organic fertilisers
point and non-point sources
wastewater treatment
River, lake, and water-supply engineering (General)
TC401-506
Physical geography
GB3-5030
Language
English
ISSN
1998-9563
2224-7955
Abstract
We analysed long-term (1992–2020) changes in fertiliser use, wastewater treatment, and river water nutrient status in Estonia (N-E Europe) in the context of changing socio-economic situations and legislation. We hypothesised that improved regulation of fertiliser usage and wastewater treatment are reflected as declining riverine nutrient concentrations, with the largest relative improvements occurring in catchments with initially high proportions of point source loading. We analysed nutrient dynamics in 16 rivers differing by catchment land use, population and livestock densities. Data on fertiliser use and wastewater treatment originated from the Statistics Estonia database, and riverine nutrient concentrations from the State Environmental Monitoring Database. We clustered the rivers by their catchment properties and analysed trends in their nutrient status. Point source nutrient loading reductions explained most of the decline in riverine nutrient concentrations, whereas application of mineral fertilisers has increased, hindering efforts to reach water quality and nutrient load targets set by the EU Water Framework Directive and the Baltic Sea Action Plan. Highest nitrogen concentrations and strongest increasing trends were found in rivers within the Nitrate Vulnerable Zone, indicating violation of the EU Nitrates Directive. To comply with these directives, resource managers must address non-point source nutrient loading from river watersheds. HIGHLIGHTS Drop in point source loading explained the decline in riverine nitrogen (N) and phosphorus (P) since 1994.; Fertiliser and wastewater management measures failed short to meet the water quality and nutrient load targets set by the EU Water Framework Directive.; Highest N concentrations and strongest increasing trends were found in rivers within the nitrate vulnerable zone violating the EU Nitrates Directive.;