학술논문

Chemically modified cellulose nanomaterial for remediation of nickel and lead from secondary runoff industrial wastewater
Document Type
article
Source
Water Practice and Technology, Vol 19, Iss 4, Pp 1185-1199 (2024)
Subject
adsorption
cellulose material
lead and nickel elimination
surface modification
wastewater
Environmental technology. Sanitary engineering
TD1-1066
Language
English
ISSN
1751-231X
Abstract
An innovative and chemically amended succinic anhydride cellulose nanomaterial (S-CNM) adsorbent was synthesized from dried stem of Eichhornia crassipes weed, and was characterized for functional groups, crystallite size, surface morphology, morphological structure and particle size using Fourier transform infrared (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET) instruments, respectively. Previously characterized S-CNM was investigated to eliminate nickel and lead from secondary runoff wastewater (SERWW). Physicochemical properties of SERWW including organic matter (OM), nutrients, total inorganic nitrogen (TIN) and total phosphorus (TP) on the elimination capabilities of heavy metals were investigated. The S-CNM adsorbent was used fruitfully to exclude nickel and lead from SERWW. The mechanism study showed that the Langmuir isotherm was suited for lead removal and Freundlich isotherm was suited for nickel removal with maximum eliminating capability (qmax) of 156.25 and 60.24 mg g−1 using the S-CNM adsorbent, respectively. The elimination kinetic process fits well with pseudo-second-order and its data recommending the materials (S-CNM) are effective for wastewater treatment. The lead and nickel uptake capacities were influenced by the presence of positively charged ions. The S-CNM adsorbent indicated excellent reproducibility and was considered as a capable adsorption resource to eliminate lead and nickel from SERWW. HIGHLIGHTS This is a novel research work because it focuses on a recent research area known as water remediation.; The material used for remediation purposes is noble and new that is environmental friendly.; The remediation technique was very cost-effective.; The material used was easily recyclable.; The material was modified by suitable chemicals that enhance the remediation processes.;