학술논문
Rapid transformation of sulfinate salts into sulfonates promoted by a hypervalent iodine(III) reagent
Document Type
article
Author
Source
Beilstein Journal of Organic Chemistry, Vol 14, Iss 1, Pp 1203-1207 (2018)
Subject
Language
English
ISSN
1860-5397
Abstract
An alternative method for forming sulfonates through hypervalent iodine(III) reagent-mediated oxidation of sodium sulfinates has been developed. This transformation involves trapping reactive sulfonium species using alcohols. With additional optimization of the reaction conditions, the method appears extendable to other nucleophiles such as electron-rich aromatic systems or cyclic ethers through a ring opening pathway.