학술논문

Process Optimization for Syngas Production from the Dry Reforming of Methane over 5Ni+3Sr/10Zr+Al Catalyst Using Multiple Response Surface Methodology
Document Type
article
Source
Advanced Materials Interfaces, Vol 11, Iss 1, Pp n/a-n/a (2024)
Subject
dry reforming of methane
feed ratio
gas hour space velocity
optimization
reaction temperature
RSM
Physics
QC1-999
Technology
Language
English
ISSN
2196-7350
Abstract
Abstract 5Ni+3Sr/10Zr+Al catalyst is synthesized using the impregnation method, characterized, and tested for dry reforming of methane. The influence of reaction temperature, feed ratio (CO2/CH4), and gas hour space velocity are examined using multiple response surface methodology through three factors in, a four‐level central composite design. Second and higher‐order regression models are applied to evaluate the interaction between the process parameters and responses. The results indicate that the reaction temperature is the most influential followed by the space velocity, while the feed ratio has a weak effect. The optimum values that maximize each of the response variables are found to be the reaction temperature at 746 °C, the space velocity of 12 000 ccg−1h−1, and the feed ratio of 0.958. Under these conditions, the predicted CH4 and CO2 conversions are 86.83% and 92.27%, respectively. While the H2/CO ratio is 1.02. On the other hand, the experimental results match the predicted ones when the optimum predicted operating conditions are used for the process. A weight loss of