학술논문

Glass-water interaction of a potassium phospho-aluminosilicate glass: Influence on mechanical behavior
Document Type
article
Source
Journal of Non-Crystalline Solids: X, Vol 18, Iss , Pp 100184- (2023)
Subject
Water in glass
Mechanical properties
Crack growth
Fatigue
Materials of engineering and construction. Mechanics of materials
TA401-492
Chemistry
QD1-999
Language
English
ISSN
2590-1591
Abstract
The mechanical behavior of a potassium phospho-aluminosilicate (KPAS) glass which is known to develop near-surface compressive stress profiles resulting from low-temperature water diffusion was explored. Region I of the macro-crack growth curve for the KPAS glass exhibited a steeper slope corresponding to a higher fatigue parameter, n, than soda-lime glass despite a lower n at crosshead speeds of 10−1–102 mm/min and no decrease in strength at lower rates in dynamic fatigue testing. The fatigue limit was easily observed in 50% RH air for the KPAS glass at velocities ~10−6–10−7 m/s giving rise to the delayed restart of cracks aged below the fatigue limit. Additionally, a 75% strength increase of the KPAS glass was measured after abraded specimens were aged for 100 days in humid air relative to specimens which were tested immediately following abrasion. The effects of swelling stress, surface stress relaxation, crack healing, and crack tip blunting are discussed.