학술논문
Coherent structural trapping through wave packet dispersion during photoinduced spin state switching
Document Type
article
Author
Source
Nature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
Subject
Language
English
ISSN
2041-1723
Abstract
Ultrafast nonadiabatic chemical dynamics during molecular photo-transformations remain challenging to describe since electronic/nuclear configurations are coupled. Here the authors use time-resolved X-ray absorption spectroscopy to probe the light-induced spin-state trapping dynamics of [Fe(bpy)3]2+beyond the Born-Oppenheimer approximation.