학술논문

New Isotherm for Multilayer Adsorption of Vapours on Non-Porous Adsorbents
Document Type
article
Author
Source
Adsorption Science & Technology, Vol 2 (1985)
Subject
Physical and theoretical chemistry
QD450-801
Language
English
ISSN
0263-6174
2048-4038
02636174
Abstract
A new three-parameter isotherm equation to describe multilayer adsorption of vapours on non-porous adsorbants is derived. The model parameters are the monolayer adsorption capacity ( m ) and two temperature dependent constants, C 1 and C ∞ , which describe the adsorbate-surface interactions in, respectively, the first and the subsequent layers. The model can successfully describe the data for multilayer adsorption of ethanol, benzene and cyclohexane on cabosil in the entire relative saturation pressure range of zero to unity.