학술논문
Airborne Observations Constrain Heterogeneous Nitrogen and Halogen Chemistry on Tropospheric and Stratospheric Biomass Burning Aerosol
Document Type
article
Author
Zachary C. J. Decker; Gordon A. Novak; Kenneth Aikin; Patrick R. Veres; J. Andrew Neuman; Ilann Bourgeois; T. Paul Bui; Pedro Campuzano‐Jost; Matthew M. Coggon; Douglas A. Day; Joshua P. DiGangi; Glenn S. Diskin; Maximilian Dollner; Alessandro Franchin; Carley D. Fredrickson; Karl D. Froyd; Georgios I. Gkatzelis; Hongyu Guo; Samuel R. Hall; Hannah Halliday; Katherine Hayden; Christopher D. Holmes; Jose L. Jimenez; Agnieszka Kupc; Jakob Lindaas; Ann M. Middlebrook; Richard H. Moore; Benjamin A. Nault; John B. Nowak; Demetrios Pagonis; Brett B. Palm; Jeff Peischl; Felix M. Piel; Pamela S. Rickly; Michael A. Robinson; Andrew W. Rollins; Thomas B. Ryerson; Gregory P. Schill; Kanako Sekimoto; Chelsea R. Thompson; Kenneth L. Thornhill; Joel A. Thornton; Kirk Ullmann; Carsten Warneke; Rebecca A. Washenfelder; Bernadett Weinzierl; Elizabeth B. Wiggins; Christina J. Williamson; Edward L. Winstead; Armin Wisthaler; Caroline C. Womack; Steven S. Brown
Source
Geophysical Research Letters, Vol 51, Iss 4, Pp n/a-n/a (2024)
Subject
Language
English
ISSN
1944-8007
0094-8276
0094-8276
Abstract
Abstract Heterogeneous chemical cycles of pyrogenic nitrogen and halides influence tropospheric ozone and affect the stratosphere during extreme Pyrocumulonimbus (PyroCB) events. We report field‐derived N2O5 uptake coefficients, γ(N2O5), and ClNO2 yields, φ(ClNO2), from two aircraft campaigns observing fresh smoke in the lower and mid troposphere and processed/aged smoke in the upper troposphere and lower stratosphere (UTLS). Derived φ(ClNO2) varied across the full 0–1 range but was typically