학술논문

Low-Cost Carbon Nanoparticles for Removing Hazardous Organic Pollutants from Water: Complete Remediation Study and Multi-Use Investigation
Document Type
article
Source
Inorganics, Vol 10, Iss 9, p 136 (2022)
Subject
carbon nanoparticles
toilet paper waste
malachite green
indigo carmine
rhodamine B
methylene blue
Inorganic chemistry
QD146-197
Language
English
ISSN
2304-6740
Abstract
Continuous waste discharge into natural water resources in many countries is a severe global issue, and seeking an effective solution is a researcher’s concern. Herein, toilet paper waste was a low-cost precursor for preparing carbon nanoparticles (TPCNPs). The characterization of TPCNPs revealed a 30 nm to 50 nm particle size, a 264 m2 g−1 surface area, and a cubical graphite lattice XRD pattern. The TPCNPs were tested for removing malachite green (MG), indigo carmine (IC), rhodamine B (RB), and methylene blue (MB) dyes from water. The solution parameters were examined for the sorption process, and a pH of 5.0 suited the MB removal, while a pH of 6.0 was suitable for MG, IC, and RB. The effect of concentration investigation showed an adsorption capacity of 110.9, 64.8, 73.5, and 98 mg g−1 for MG, IC, RB, and MB, respectively. The sorption of the four dyes fitted the Langmuir isotherm model; it was exothermic and spontaneous. The water remediation was tested using groundwater and seawater samples (GW and SW) spiked with pollutants. It is worth mentioning that one treatment sufficed for the remediation of GW and SW contaminated by 5 mg L−1 concentration, while a double treatment was required for 10 mg L−1 pollution in both samples.