학술논문

Improved photocatalytic performance of reduced zinc oxide (ZnO) novel morphology of astray like microstructure under solar light irradiation
Document Type
article
Source
Materials Science for Energy Technologies, Vol 2, Iss 2, Pp 181-186 (2019)
Subject
Materials of engineering and construction. Mechanics of materials
TA401-492
Energy conservation
TJ163.26-163.5
Language
English
ISSN
2589-2991
Abstract
Zinc oxide (ZnO) microstructures were successfully fabricated by using the template free hydrothermal growth method. Crystalline phase, morphology, and elemental composition had been characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), and energy dispersive X-ray spectroscopy (EDS). FESEM graphs had showed that hexagonal astray like morphology along micro sized particles. Synthesized microstructures of ZnO were hydrogenated at high temperature 500 °C to get reduced ZnO microstructures. Furthermore, ultraviolet-visible-near infrared (UV–Vis-NIR) spectroscopy had been employed to determine the optical absorbance of ZnO microstructures. The direct optical band gap of 2.1 eV was acquired by using Davis-Mott model for reduced ZnO microstructures. Hydrogenation of ZnO microstructures made the material photoactive under visible light region. Visible light active (VLA) performance of reduced ZnO microstructures improved photocatalytic degradation of pollutants under solar light irradiation. Photocatalytic performance of prepared ZnO microstructures and reduced ZnO microstructures were investigated by using methyl orange under solar light irradiation.