학술논문

Structural modification of carbon black for improving the dielectric performance of epoxy based composites
Document Type
article
Source
Advanced Industrial and Engineering Polymer Research, Vol 1, Iss 1, Pp 111-117 (2018)
Subject
Polymers and polymer manufacture
TP1080-1185
Engineering (General). Civil engineering (General)
TA1-2040
Language
English
ISSN
2542-5048
Abstract
To explore a feasible strategy for improving the dielectric properties of carbon black (CB)/epoxy composites, CB@TiO2 core-shell particles and CB-SiO2 hybrid particles were prepared and incorporated into epoxy. The microstructures of CB, CB@TiO2, and CB-SiO2 particles, as well as the dielectric properties of their epoxy-based composites were investigated. The results showed that the composites containing CB-SiO2 hybrid particles possessed a higher dielectric constant than the ones containing pristine CB. The dielectric constant of the composite with 20.0 vol% CB-SiO2 reached 52.68 (1 kHz), which was ca. 4 times greater than that of the one containing 20.0 vol% pristine CB. Meanwhile, the composites containing CB@TiO2 core-shell particles exhibited suppressed values of dielectric loss. The permittivity of the composite with 20.0 vol% CB@TiO2 reached 19.52 (1 kHz), while its dielectric loss remained low (0.047 at 1 kHz). These results indicated that the dielectric properties of epoxy composites could be enhanced with the introduction of modified fillers. Keywords: Carbon black, Epoxy, Composite, Dielectric performance