학술논문

Electro-oxidative quinylation of sulfides to sulfur ylides in batch and continuous flow
Document Type
article
Source
iScience, Vol 27, Iss 1, Pp 108605- (2024)
Subject
Chemistry
Continuum mechanics
Electrochemistry
Science
Language
English
ISSN
2589-0042
Abstract
Summary: An unprecedented strategy for preparing a series of sulfur ylides through electro-oxidative quinylation of sulfides in batch and continuous flow has been developed. Good to excellent yields were obtained with excellent functional group compatibility and good concentration tolerance under exogenous oxidant- and transition metal-free conditions. Advantageously, this electrosynthesis methodology was scalable with higher daily production and steady production was achieved attributing to the use of micro-flow cells.