학술논문

Indium Doping of Lead-Free Perovskite Cs2SnI6
Document Type
article
Source
Frontiers in Chemistry, Vol 8 (2020)
Subject
perovskite photovoltaics
cesium iodostannate(IV)
solid solution
Raman spectroscopy
optical characteristics
Chemistry
QD1-999
Language
English
ISSN
2296-2646
Abstract
Structure and properties of an inorganic perovskite Cs2SnI6 demonstrated its potential as a light-harvester or electron-hole transport material; however, its optoelectronic properties are poorer than those of lead-based perovskites. Here, we report the way of light tuning of absorption and transport properties of cesium iodostannate(IV) Cs2SnI6 via partial heterovalent substitution of tin for indium. Light absorption and optical bandgaps of materials have been investigated by UV-vis absorption and photoluminescent spectroscopies. Low-temperature electron paramagnetic resonance spectroscopy was used to study the kind of paramagnetic centers in materials.