학술논문
Electric Energy Storage Effect in Hydrated ZrO2-Nanostructured System
Document Type
article
Author
Alexander S. Doroshkevich; Andriy I. Lyubchyk; Boris L. Oksengendler; Tatyana Yu. Zelenyak; Nurbol O. Appazov; Andriy K. Kirillov; Tatyana A. Vasilenko; Alisa A. Tatarinova; Oksana O. Gorban; Viktor I. Bodnarchuk; Nadejda N. Nikiforova; Maria Balasoiu; Diana M. Mardare; Carmen Mita; Dorin Luca; Matlab N. Mirzayev; Asif A. Nabiyev; Evgeni P. Popov; Anca Stanculescu; Tatyana E. Konstantinova; Yulia V. Aleksiayenak
Source
Nanomaterials, Vol 12, Iss 11, p 1783 (2022)
Subject
Language
English
ISSN
12111783
2079-4991
2079-4991
Abstract
The dimensional effect of electric charge storage with a density of up to 270 μF/g by the hydrated ZrO2-nanoparticles system was determined. It was found that the place of localization of different charge carriers is the generalized heterophase boundary-nanoparticles surface. The supposed mechanism of the effect was investigated using the theory of dispersed systems, the band theory, and the theory of contact phenomena in semiconductors, which consists of the formation of localized electronic states in the nanoparticle material due to donor–acceptor interaction with the adsorption ionic atmosphere. The effect is relevant for modern nanoelectronics, microsystem technology, and printed electronics because it allows overcoming the basic physical restrictions on the size, temperature, and operation frequency of the device, caused by leakage currents.