학술논문
Dialkylaminosubstituierte Phosphiniminophosphonium-Organofluorphosphate und Mono- bzw. Dichlorphosphazene / Dialkylamino Substituted Phosphine Iminophosphonium Organofluorophosphates and Mono- and Dichlorophosphazenes
Document Type
research-article
Source
Zeitschrift für Naturforschung B. 46(4):495-499
Subject
Language
English
ISSN
1865-7117
0932-0776
0932-0776
Abstract
The reaction of N-trimethylsilylphosphine imines, Me3SiN=PR1R2R3, and Me3SiN=P(R1R2)—N=PR1R2R3 (R1, R2, R3 = hydrocarbon or NR, groups) with the fluorophosphoranes PhPF4 and Ph2PF3 and with phosphorus trichloride has furnished phosphine iminophosphonium organofluorophosphates, involving the anions [PhPF5]- or [Ph2PF4]-, and mono- or dichlorophosphino diphosphazenes, respectively. The characterization of these compounds by 1H, 19F and 31P NMR spectroscopy is described.