학술논문
Formation of ruthenium nanoparticles inside aluminosilicate nanotubes and their catalytic activity in aromatics hydrogenation: the impact of complexing agents and reduction procedure
Document Type
research-article
Author
Source
Pure and Applied Chemistry. 92(6):909-918
Subject
Language
English
ISSN
1365-3075
0033-4545
0033-4545
Abstract
Ruthenium particles with size from 1 to 7 nm were formed by reduction of ruthenium complexes with urea, ethylenediaminetetraacetic acid, acetone azine, 1,2-Bis(2-furylmethylene)hydrazine) inside halloysite nanotubes. Catalysts of different morphology with Ru content from 0.75 to 0.93 %wt. were obtained using NaBH4 or H2 as reducing agents and tested in benzene hydrogenation as a model reaction. NaBH4 reduced catalysts showed similar catalytic activity with 100 % benzene conversion after 1.5 h. Reduction with H2 resulted in a decrease of catalytic activity for all samples. High benzene conversion was achieved only in the case of 1,2-Bis(2-furylmethylene)hydrazine and ethylenediaminetetraacetic acid. It was concluded that the thermal stability of complexing agents plays a key role in activity of catalysts reduced with H2.