학술논문

NMR studies on polarized12B implanted in highly oriented pyrolytic graphite
Document Type
Article
Source
Hyperfine Interactions; July 1988, Vol. 39 Issue: 3 p253-267, 15p
Subject
Language
ISSN
03043843; 15729540
Abstract
Abstract: NMR measurements on12B nuclei implanted in a thin sheet of highly oriented pyrolytic graphite (Grafoil) have been made to study the magnitude of the polarization of12B and its electric quadrupole coupling. The magnitude of the residual polarization of12B held in carbon material is of crucial importance to the experiment measuring the average polarization of12B produced in the muon capture by12C. It was found that the polarization of12B can be maintained at 101.02.2% in Grafoil under a magnetic field of 3 kG. The electric quadrupole coupling was determined to bee 2 qQ/h=+1207.38.2 kHz. From the magnitude and the sign of the electric field gradienteq, the location of12B was found to be a substitutional site in the carbon lattice. The anomalous B-C bond involving thesp 2 hybrid orbitals with partially filledp z electrons is also discussed.