학술논문

The simultaneous double Diels-Alder addition of 1,1-bis(3,5-dimethylfur-2-yl)ethane; toward a new, asymmetric synthesis of long-chain polypropionate fragments and analogues
Document Type
Article
Source
Tetrahedron Letters; January 1996, Vol. 37 Issue: 24 p4149-4152, 4p
Subject
Language
ISSN
00404039
Abstract
The double cycloaddition of 1,1-bis(3,5-dimethylfur-2-yl)ethane to diethyl (E,E)-4-oxohepta-2,5-diene-1,7-dioate gave a single bis-adduct, the hydroboration of which with IpcBH 2allows the creation of optically active polycyclic systems that are potential precursors of long-chain polypropionate fragments.