학술논문
High viscosity of ionic liquids causes rate retardation of Diels-Alder reactions
Document Type
Article
Author
Source
SCIENCE CHINA Chemistry; 20240101, Issue: Preprints p1-5, 5p
Subject
Language
ISSN
16747291; 18691870
Abstract
Abstract: Second order rate constants, k 2 have been determined for three bi-molecular Diels-Alder reactions to demonstrate that the high viscosity of ionic liquids can be a detrimental property in carrying out Diels-Alder reactions, if ionic liquids are employed as solvent media. It is possible to enhance the reaction rates of the reaction if a co-solvent is mixed in pure ionic liquid used as a solvent.