학술논문

Valanimycin Biosynthesis: Investigations of the Mechanism of Isobutylhydroxylamine Incorporation

Document Type

Article

Author

Tao, T.; Alemany, L. B.; Parry, R. J.

Source

Organic Letters; April 2003, Vol. 5 Issue: 8 p1213-1215, 3p

Subject

Language

ISSN

15237060; 15237052

Abstract

The incorporation of [¹⁵N, ¹⁸O]-isobutylhydroxylamine into the antibiotic valanimycin by Streptomyces viridifaciens has been shown to proceed with loss of the ¹⁸O label, thereby demonstrating that the azoxy oxygen atom of valanimycin is not derived from the oxygen atom of isobutylhydroxylamine.

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