학술논문
Structure et proprietes chimiques du complexe Cp(DPPE)FeCOPh. Preparation de complexes carbeniques
Document Type
Article
Author
Source
Journal of Organometallic Chemistry; August 1977, Vol. 135 Issue: 3 p361-372, 12p
Subject
Language
ISSN
0022328X
Abstract
Cp(DPPE)Fe(COPh) (A) can be prepared either by reaction of benzoyl chloride with the inorganic Grignard reagent Cp(DPPE)FeMgBr or by irradiation of Cp(CO)2Fe(COPh) in the presence of DPPE. Complex A Shows a particularly low carbonyl absorption in the infrared spectrum: 1510 cm−1. The crystal structure determination shows a distorted geometry for the benzoyl group. A is a precursor for carbene complexes which do not contain carbonyl ligands.